Journal
CATALYSIS LETTERS
Volume 124, Issue 1-2, Pages 34-38Publisher
SPRINGER
DOI: 10.1007/s10562-008-9503-8
Keywords
graphite oxide; palladium; nanoparticle; X-ray diffraction; transmission electron microscopy; alkyne hydrogenation; turnover frequency; selectivity
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Graphite oxide (GO) was utilized as a novel host material for Pd nanoparticles of controlled crystallite size. Immobilization of the Pd nanoparticles from a stable Pd sol in GO resulted in the formation of organophilic Pd-GO, a layer-structured material, which was characterized by ICP-AES, XRD and TEM. Pd-GO proved to be a highly active and stereoselective catalyst in liquid-phase alkyne hydrogenations under mild conditions.
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