Hydrodeoxygenation of vanillin over carbon nanotube-supported Ru catalysts assembled at the interfaces of emulsion droplets

Carbon nanotube supported ruthenium catalysts, assembled at the water/oil interfaces, show excellent activity and selectivity for the hydrodeoxygenation of the bio-oil model compound of vanillin under mild conditions (1 MPa, 150 degrees C). Based on a direct fluorescence image, the Ru/CNT catalysts are mainly distributed on the surface of the emulsion droplets, forming a Pickering emulsion. Simultaneous reaction and separation of the products are achieved in the constructed emulsions, which have great potential in the simplifications of the isolation and purification stages for bio-oil refining. Crown Copyright (C) 2014 Published by Elsevier B.V. All rights reserved.