Journal
CATALYSIS COMMUNICATIONS
Volume 56, Issue -, Pages 50-54Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2014.06.025
Keywords
Amines; Cu(I) catalyst; Dehydrogenation; Azo derivatives; Hydrazine derivatives
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Funding
- DST-SERB-Fast Track Scheme, Govt. of India [SR/FT/CS-93/2011]
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An efficient protocol for the synthesis of a variety of azobenzenes and hydrazines from aromatic amines under mild reaction conditions is developed using Cu(I) catalyst. The copper cataylst used in this study comprises of CuBr, DMAP and AIBN. The plausible proposed mechanism for this dehydrogenative homo coupling of aromatic amines is depicted. (C) 2014 Elsevier B.V. All rights reserved.
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