Journal
CATALYSIS COMMUNICATIONS
Volume 54, Issue -, Pages 61-65Publisher
ELSEVIER
DOI: 10.1016/j.catcom.2014.05.024
Keywords
[AuCl2(phen)]Cl; Acetylene hydrochlorination
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Funding
- National Basic Research Program of China (973 Program) [2012CB720302]
- Developing Plan of Changjiang Scholars and Innovative Research Team [IRT1161]
- National Natural Science Foundation of China (NSFC) [21366027]
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Herein, we reported on the application of an Au(III)/Schiff-based catalyst in acetylene hydrochlorination reaction. The [AuCl2(phen)]Cl catalyst exhibited excellent stability, and acetylene conversion was maintained at >90% after 40 h of operation. The excellent stability of the [AuCl2(phen)]Cl catalyst was attributed to the presence of the 1,10-phenanthroline ligand that partially inhibited the reduction of the Au3+ active component. (C) 2014 Elsevier B.V. All rights reserved.
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