Journal
CATALYSIS COMMUNICATIONS
Volume 43, Issue -, Pages 11-15Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2013.08.019
Keywords
TiO2 nanorod and nanosphere; Photocatalysis; Visible light; Oxygen evolution
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Funding
- WCU (World Class University) program through the National Research Foundation of Korea
- Ministry of Education, Science and Technology [R31-10013]
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The enhancement of O-2 evolution via the oxidation of water on {102} facet dominant nitrogen-doped TiO2 (N-TiO2) nanorods is described. N-doped TiO2 nanosphere and nanorod were synthesized and subsequent NH3 treatment. 3 atomic% of nitrogen was incorporated into both anatase TiO2 nanocrystals. They show same band gap energies of 2.8 eV and similar lifetime of photo-exciton. The surface of N-doped TiO2 nanorod, however, presents much more dominant amount of {102} facets than that of nanosphere. The low overpotential of the {102} facets results in the selective generation of O-2 with the simultaneous suppression of the photocatalytic formation of center dot OH. (C) 2013 Elsevier B.V. All rights reserved.
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