Journal
CATALYSIS COMMUNICATIONS
Volume 45, Issue -, Pages 104-108Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2013.11.005
Keywords
TS-1; Hierarchical; Zeolite; Open voids
Categories
Funding
- National Natural Science Foundation of China [21276180]
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A hierarchical titanium silicate (TS-1) that possesses large open voids has been prepared by using a dissolution/re-crystallization process. Carbon black was introduced as a hard template during the synthesis process to generate defects both inside and on the surface of crystals, then TPAOH post-treatment was applied, as a result, a novel TS-1 zeolite crystal with large open voids was successfully synthesized. The synthesized hierarchical TS-1 was characterized by XRD, FTIR, SEM, TEM and N-2 physisorption. Compared with the traditional TS-1 and hollow TS-1, the activity of hierarchical TS-1 in cyclohexanone ammoximation was improved and attributed to the macropores that linked the voids inside the zeolite directly to the outer surface. (C) 2013 Elsevier B.V. All rights reserved.
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