Journal
CATALYSIS COMMUNICATIONS
Volume 35, Issue -, Pages 101-104Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2013.02.013
Keywords
Polyoxometalates; MOFs; Oxygen; Benzene; Phenol
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Funding
- National Basic Research Program of China [2009CB623505]
- National Natural Science Foundation of China [21273225]
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Three novel catalysts named as PMo12-nVn@HKUST-1 (n=1-3) were designed and obtained through encapsulating vanadium-doped Keggin polyoxometalates (POMs) PMo12-n V-n into the framework HKUST-1 (also denoted as Cu-3(BTC)(2), MOF-199). The character structure of PMo12-n V-n@HKUST-1 was elucidated through the single crystal XRD of PMo11V@HKUST-1. Reaction rate could be greatly enhanced by PMo12-n V-n@HKUST-1 in liquid hydroxylation of benzene with O-2. Only in 20 min, a high TOF (442 h(-1)) of PMo9V3@HKUST-1 was obtained. (C) 2013 Elsevier B.V. All rights reserved.
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