4.6 Article

Mild oxidative alkane functionalization with peroxides in the presence of ferrocene

Journal

CATALYSIS COMMUNICATIONS
Volume 31, Issue -, Pages 32-36

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2012.11.003

Keywords

Alkanes; Homogeneous catalysis; Hydrogen peroxide; Hydrocarboxylation; Hydroperoxidation; Iron complexes

Funding

  1. Russian Foundation for Basic Research [12-03-00084-a]
  2. Fundacao para a Ciencia e a Tecnologia, FCT [PTDC/QUI-QUI/102150/2008, PEst-OE/QUI/UI0100/2011, SFRH/BPD/34926/2007]
  3. Fundação para a Ciência e a Tecnologia [PTDC/QUI-QUI/102150/2008] Funding Source: FCT

Ask authors/readers for more resources

Ferrocene in an unexpected emploi: alkanes can be efficiently oxygenated by H2O2 in the presence of catalytic amounts of this well-known organometallic compound in combination with pyrazine-2-carboxylic acid or 2,2'-bipyridine. Saturated hydrocarbons, RH, are also transformed into carboxylic acids, RCOOH, when reacted with the ferrocene/CO/S2O82-/H2O system in acetonitrile solution. (C) 2012 Elsevier B.V. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.6
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available