Journal
CATALYSIS COMMUNICATIONS
Volume 21, Issue -, Pages 42-45Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2012.01.020
Keywords
Olefin metathesis; Hybrid catalyst; Ruthenium complexes; Mesoporous molecular sieve SBA-15
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Funding
- Grant Agency of the Academy of Sciences of the Czech Republic [IAA400400805]
- Academy of Sciences of the Czech Republic [KAN100400701]
- Grant Agency of the Czech Republic [203/08/H032]
- Foundation for Polish Science
- European Union
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Ruthenium complex 3b bearing chelating carboxylate ligand was immobilized on mesoporous molecular sieve SBA-15 via cleavage of carboxylate by fluorocarboxylic acid groups introduced on the support surface. The hybrid olefin metathesis catalyst Ru/L/SBA-15, prepared straightforward without use of silver salts, exhibited high activity and selectivity in model metathesis reactions and low ruthenium leaching. (C) 2012 Elsevier B.V. All rights reserved.
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