Journal
CATALYSIS COMMUNICATIONS
Volume 20, Issue -, Pages 29-35Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2011.12.037
Keywords
Semi-embedded nanoparticles; Ru-OMC; Ordered mesoporous carbon; Benzene hydrogenation
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Funding
- Natural Science Foundation of China (NSFC) [20803064]
- Natural Science Foundation of Zhejiang Provence [Y4090348]
- Qianjiang Talent Project in Zhejiang Province [2010R10039]
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Ordered mesoporous ruthenium containing carbon (Ru-OMC) catalyst with semi-embedded uniform Ru particle distribution was synthesized by using RuCl3/SBA-15 as a hard template. The sucrose both acts as the carbon precursor and Ru3+ stabilizer. The use of RuCl3/SBA-15 makes more exposed Ru surface available for reactants. The turnover frequency of the Ru-OMC catalyst for hydrogenation of benzene reaches ca. 35,000 h(-1) at 4 MPa, 110 degrees C, which is 12 times improvement compared with that of Ru/OMC catalyst prepared by impregnation. The Ru-OMC catalyst can be recycled more than 9 times without much loss of performance and aggregation of Ru nanoparticles. (C) 2012 Elsevier B.V. All rights reserved.
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