Journal
CATALYSIS COMMUNICATIONS
Volume 29, Issue -, Pages 101-104Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2012.09.032
Keywords
Nitroalkanes; C - C bond formation; Henry reaction; Metal-organic frameworks
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Funding
- National Natural Science Foundation of China [20971109, 21036006]
- Program for Changjiang Scholars and Innovative Research Team in Chinese Universities [IRT0980]
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Ethylenediamine moieties with different amounts were incorporated into the metal-organic framework MIL-101 to prepare the amino-functionalized MIL-101 materials, which were used as heterogeneous catalysts in the one-pot synthesis of nitroalkenes via the Henry reaction. Various reaction conditions were optimized. Under the optimized conditions, the selectivity towards nitroalkenes is extremely high in combination with nearly complete conversion of the reactant nitroalkanes. The amino-functionalized MIL-101 behaves as a true heterogeneous catalyst, can be easily recovered by filtration, and can be reused at least twice without significant loss of its catalytic performance. (C) 2012 Elsevier B.V. All rights reserved.
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