4.6 Article

Boron nitride as an alternative support of Pd catalysts for the selective oxidation of lactose

Journal

CATALYSIS COMMUNICATIONS
Volume 29, Issue -, Pages 170-174

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2012.10.007

Keywords

Boron nitride; Lactose; Palladium; Oxidation; Alumina

Funding

  1. Fonds de la Recherche Scientifique (FRS-FNRS)
  2. Federation Wallonie-Bruxelles
  3. Belgian National Lottery
  4. Universite Catholique de Louvain
  5. Belgian State (Belgian Science Policy, IAP Project INANOMAT) [P6/17]

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The potential of boron nitride as innovative support for the selective oxidation of carbohydrates has been evaluated. Pd/h-BN catalysts as well as Pd/alpha-Al2O3 have been synthesized by two different methods for comparison: dry impregnation and deposition-precipitation. It is shown that BN is a suitable alternative to alumina and carbon for sugar oxidation in liquid phase. Very active and selective Pd/h-BN catalysts were obtained by the two synthetic methods under consideration. (C) 2012 Elsevier B.V. All rights reserved.

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