Journal
CATALYSIS COMMUNICATIONS
Volume 16, Issue 1, Pages 144-149Publisher
ELSEVIER
DOI: 10.1016/j.catcom.2011.09.011
Keywords
Iridium catalyst; Glycerol; Lactic acid; 1,2-propanediol; Hydrogenolysis
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Funding
- EU [NMP2-CT2005-515792]
- French Minister of Research and Education
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Here, we report the transformation of glycerol alkaline solutions in the presence of supported iridium catalysts under either reductive or inert atmosphere at 453 K. It was shown that under H-2, the expected 1,2-PDO issued from hydrogenolysis of the triol was the main product while under He, lactic acid was formed predominantly via Cannizzaro rearrangement. (C) 2011 Elsevier B.V. All rights reserved.
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