Journal
CATALYSIS COMMUNICATIONS
Volume 11, Issue 8, Pages 732-735Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2010.02.004
Keywords
Vanadyl sulfate; Catalytic oxidation; Oxygen; Alcohols; TEMPO
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Funding
- Natural Science Foundation of China [20736010, 20803074]
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Inexpensive vanadyl sulfate was developed in combination with 2.2,6,6-tetramethyl-piperidyl-1-oxyl (TEMPO) for catalytic oxidation of alcohols with molecular oxygen. A wide range of alcohols were oxidized to the corresponding carbonyl compounds in good conversions under mild conditions. No ligands or extra bases were used. Acetonitrile was the suitable solvent to keep the high activity of this system. (C) 2010 Elsevier B.V. All rights reserved.
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