4.6 Article

Sulfonic acid functionalized mesoporous SBA-15 for one-pot synthesis of substituted aryl-14H-dibenzo xanthenes and bis(indolyl) methanes

Journal

CATALYSIS COMMUNICATIONS
Volume 11, Issue 14, Pages 1148-1153

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2010.06.004

Keywords

Xanthenes; Bis (indolyl) methanes; SBA-15; Heterogeneous catalysis

Funding

  1. Birla Institute of Science and Technology
  2. DST (Department of Science and Technology-New Delhi, Govt. of India)
  3. CSIR (Council of Scientific and Industrial Research)

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The comparative catalytic activity studies of biologically and industrially important compounds such as Xanthenes and bis (indolyl) methanes were evaluated over propylsulfonic acid functionalized SBA-15/SO(3)H. The material was characterized via standard characterization techniques such as Powder X-ray diffraction, FTIR. Temperature programmed desorption studies of NH(3). The catalytic performance of SBA/SO(3)H under environmentally benign conditions results in high yield of xanthenes compared to bis (indolyl) methanes and finally the mechanism for both the reactions were proposed. (C) 2010 Elsevier B.V. All rights reserved.

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