Journal
CATALYSIS COMMUNICATIONS
Volume 9, Issue 14, Pages 2407-2410Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2008.05.039
Keywords
N-hydroxyphthalimide; M/ZSM-5; cyclohexane; oxidation
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A catalytic system consisting of ZSM-5 supported metal ions (M/ZSM-5) and N-hydroxyphthalimide (NHPI) for the selective oxidation of cyclohexane with dioxygen was reported, and the catalytic activity of various M/ZSM-5 was investigated. Cyclohexane was successfully oxidized in good conversion, the highest conversion of cyclohexane could be obtained using Co(II)/ZSM-5 and NHPI, however, the highest selectivity of adipic acid was from Mn(II)/ZSM-5 and NHPI The stability and recycling of the catalyst were also reviewed. (C) 2008 Elsevier B.V. All rights reserved.
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