The active phase of Au-Pd/Al2O3 for CO oxidation

Au-Pd/Al2O3 catalyst was prepared by modified impregnation method. It was found that the catalyst calcined in air at 473 K showed higher CO oxidation activity in comparison with the catalysts treated at other temperature. Nitrogen adsorption, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and X-ray absorption near edge structure spectroscopy (XANES) techniques were employed to study the relationship between the surface/bulk structures of these catalysts and their catalytic performance. The results indicated the higher activity was attributed to the smaller pore volume and co-existence of PdO and Au-o in their surface. The formation of AuxPdy alloy was unfavorable for the catalytic reaction. (C) 2008 Elsevier B.V. All rights reserved.