4.7 Article

Bidentate amidine ligands for nickel(0)-mediated coupling of carbon dioxide with unsaturated hydrocarbons

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 22, Pages 2568-2569

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b411802b

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Novel bidentate amidines were designed and synthesized as easily available electron-donating N-ligands for Ni-0-mediated coupling of carbon dioxide with alkynes or allenes, and high regioselectivity was achieved even for the carboxylation of aryl substituted internal alkynes.

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