4.7 Article

Formation of racemic crystals of transition metal complexes by grinding 1 : 1 mixtures of enantiomeric crystals

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 24, Pages 2858-2859

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b409006c

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Grinding a 1 : 1 enantiomeric mixture of chiral transition metal complex crystals and subsequent annealing afforded crystals of a racemic compound by diffusion and rearrangement of component molecules, without melting and without racemization of each enantiomeric species.

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