Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 18, Pages 2060-2061Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b407693a
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A new robust fluorinated (OC)Ru(salen) complex was designed on the basis of an X-ray structure of its parent complex to show improved turnover numbers (up to 878) and enantioselectivities (up to 99%) in aziridination reactions using p-toluenesulfonyl (Ts) or p-nitrobenzenesulfonyl (Ns) azide as the nitrene precursor; the latter is synthetically advantageous since the Ns group is N-protecting and can be removed under mild conditions.
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