Journal
CARBON
Volume 42, Issue 3, Pages 485-495Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2003.12.070
Keywords
carbon fibers; pitch; activation; chemical structure; adsorption properties
Ask authors/readers for more resources
Pure and silver-containing carbon fibers were prepared from isotropic pitch precursors supplied by Conoco, Inc., and a Korean research team and activated in carbon dioxide to varying degrees of burn-off. The specific activation rates for the carbon fibers were measured as well as the nitrogen adsorption characteristics of the activated carbon fibers. Scanning electron microscopy was used to investigate the surface morphology and the behavior of silver particles during the activation process. Molecular composition of the two pitch precursors was determined using a gas chromatograph mass spectrometer and a MALDI TOF mass spectrometer. Results showed that specific surface area increased with the burn-off, and the trends were similar for the pure and silver-containing fibers formed from both isotropic pitch precursors. However, the catalytic behavior of silver during activation, the activation rate, and even the pore characteristics of the activated fiber were found to be dependent on the molecular composition of the precursor pitch. (C) 2004 Elsevier Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available