Journal
RAPID COMMUNICATIONS IN MASS SPECTROMETRY
Volume 18, Issue 22, Pages 2601-2611Publisher
WILEY
DOI: 10.1002/rcm.1663
Keywords
-
Ask authors/readers for more resources
Neutral and cationic pyrrolidine-fused chlorins and isobacteriochlorins derived from mesotetrakis(pentafluorophenyl)porphyrin undergo cycloreversion reactions in the gas phase, either when desorbed from a liquid matrix by ion bombardment or when electrosprayed. Cycloreversion occurs through loss of either neutral or charged moieties, with and without hydrogen and methyl radical migration, and both as high- and low-energy collision processes. For the doubly charged isobacteriochlorin, one-electron reduction with methyl loss occurs under ion bombardment and electrospray, through hypervalent pyrrolidinium radical formation. Copyright (C) 2004 John Wiley Sons, Ltd.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available