Journal
DALTON TRANSACTIONS
Volume -, Issue 10, Pages 1524-1526Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b404820b
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Co-crystallisation of the anionic cyanometallate chromophore [Ru(bipy)(CN)(4)](2-) with Yb(III) provides coordination polymers or oligomers containing Ru-CN-Yb bridges; in [K(H2O)(4)][Yb(H2O)(6)][Ru(bipy)(CN)(4)](2) . 5H(2)O Ru --> Yb energy-transfer (k > 5 x 10(6) s(-1)) results in partial quenching of the Ru-based luminescence and sensitised near-IR luminescence from the Yb(III) unit.
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