Journal
DALTON TRANSACTIONS
Volume -, Issue 10, Pages 1626-1634Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b401056f
Keywords
-
Categories
Ask authors/readers for more resources
The paramagnetic complexes (Tm-tBu) CoX ( X = Cl, Br, I) have been readily prepared and structurally characterized and provide a convenient entry into cobalt(II) tris( mercaptoimidazolyl) borate chemistry. A number of derivatives, including mononuclear triphenylphosphine adducts [(Tm-tBu) Co(PPh3)] X and dinuclear compounds [Co-2(Tm-tBu)(2)X] Y, have been prepared in order to ascertain whether cobalt is a reliable surrogate for zinc in biological systems, particularly in sulfur-rich coordination environments. The structure of the first cobaltaboratrane is also reported.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available