The effect of H-2 treatment on the activity of activated carbon for the oxidation of organic contaminants in water and the H2O2 decomposition

In this work, hydrogen peroxide reactions, i.e. H2O2 decomposition and oxidation of organics in aqueous medium, were studied in the presence of activated carbon. It was observed that the carbon pre-treatment with H-2 at 300, 500, 700 and 800 degreesC resulted in an increase in activity for both reactions. The carbons were characterized by BET nitrogen adsorption, thermogravimetric analyses (TG), temperature programmed reduction (TPR), electron paramagnetic resonance (EPR), iodometric titration and determination of the acid/basic sites. TPR experiments showed that activated carbon reacts with H-2 at temperatures higher than 400 degreesC. The treatment produces a slight increase in the surface area. EPR analyses indicate the absence of impaired electrons in the carbon. lodometric titrations and TG analyses suggested that the treatment with H-2 generates reduction sites in the carbon structure, with concentration of approximately 0.33, 0.53, 0.59, 0.65 and 0.60 mmol/g for carbons treated at 25, 300, 500, 700 and 800 degreesC, respectively. It was also observed the appearance of basic sites which might be related to the reduction sites. It is proposed that these reducing sites in the carbon can activate H2O2 to generate HO* radicals which can lead to two competitive reactions, i.e. the hydrogen peroxide decomposition or the oxidation of organics in water. (C) 2004 Elsevier Ltd. All rights reserved.