Journal
JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN
Volume 73, Issue 1, Pages 33-35Publisher
PHYSICAL SOC JAPAN
DOI: 10.1143/JPSJ.73.33
Keywords
chemical physics; homochirality; enantiometric excess; stereochemistry; rate equation
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The nonlinear autocatalysis of the chiral substance is shown to achieve homochirality in a closed system, if the back reaction is included. Asymmetry in the concentration of two enantiomers or enantiometric excess increases due to the nonlinear autocatalysis. Furthermore, when the back reaction is taken into account, the reactant supplied by the decomposition of the enantiomers is recycled to produce more of the dominant enantiomer, and eventually homochirality is established.
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