4.3 Article

Stereoselective synthesis of cis-1-aryl-2-benzoyl-3,3-dicyanocyclopropanes in the presence of KF center dot 2H(2)O

Journal

SYNTHETIC COMMUNICATIONS
Volume 34, Issue 20, Pages 3785-3792

Publisher

MARCEL DEKKER INC
DOI: 10.1081/SCC-200032500

Keywords

arsonium ylide; cis-cyclopropane; cyclopropanation; potassium fluoride dihydrate; stereoselective synthesis

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KF (.) 2H(2)O was found to be a highly efficient base for synthesis of cis-1,2-cyclopropanes with arsonium salt and olefins. The advantages of the process are mild reaction condition, easy workup, excellent yields, and high stereoselectivity.

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