Morphology and sintering behaviour of yttria stabilised zirconia (8-YSZ) powders synthesised by spray pyrolysis

This work is focused on the synthesis of nano-crystallised yttria stabilised zirconia (YSZ) powders by the spray pyrolysis method, the aim of the study being a better understanding of the influence of the spray pyrolysis parameters on the morphology of the produced powders. Spray pyrolysed powder consists of polycrystalline particles, which are spherical. Each particle consists of nanometric primary grains. The morphology of these polycrystalline particles was characterised by scanning electron microscopy (SEM), helium pycnometry, thermogravimetric analysis (TGA) and mass spectroscopy (MS), and the results are compared. Thus, particle size, particle size distribution and particle porosity were determined and correlated to the process parameters. Finally, by dilatometric measurements, sintering curves of pellets prepared from different sets of powders were analysed in regard of their morphologies. Two main conclusions could be deduced from these studies. Firstly, the process parameters influence both internal porosity and particle size distribution of the synthesised powders. Secondly, the morphologies of the spray pyrolysed nano-powders lead to particularly high sintering activities. (C) 2004 Elsevier Ltd and Techna S.r.l. All rights reserved.