Journal
HELVETICA CHIMICA ACTA
Volume 87, Issue 11, Pages 2919-2925Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/hlca.200490263
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Four new highly oxygenated guaiane lactones, menverins A-D (1-4), were isolated from the gorgonian Menella verrucosa (BRUNDIN) from the South China Sea. Their structures and relative configurations were elucidated on the basis of spectroscopic data. All compounds contain a conjugated alpha-methyl-substituted alpha,beta-unsaturated gamma-lactone moiety, a C(8)=C(9) conjugated with the gamma-lactone moiety, and an exocyclic methylene group at C(4) (trivial numbering).
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