Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 346, Issue 1, Pages 33-36Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200303144
Keywords
beta-acylamino acrylates; enantioselective catalysis; hydrogenation; monophosphite ligands; rhodium
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Chiral rhodium(l) complexes bearing monophosphite ligands, prepared from chiral Binol and (L)-menthol, were found to be efficient catalysts for the asymmetric hydrogenation of beta-acylamino acrylates with ee values up to 94%.
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