Journal
ARKIVOC
Volume -, Issue -, Pages 109-129Publisher
ARKAT USA INC
DOI: 10.3998/ark.5550190.0005.414
Keywords
alkene ligands; macrocycles; heterocycles; olefin complexes; catalysis
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(E,E,E)- 1,6,11-Tris(arenesulfonyl)-1,6,11-triazacyclopentadeca-3,8,11-trienes, 1, are prepared from arenesulfonamides and trans-1,4-dibromo-2-butene. Macrocycles 1 coordinate palladium(0), platinum(0), and silver(I), and the palladium complexes are useful and reutilizable catalysts or precatalysts in Suzuki cross-couplings, butadiene telomerizations, hydroarylation of alkynes, and in the Heck reaction. Structurally related macrocycles are also available by similar synthetic procedures.
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