Journal
NEW JOURNAL OF CHEMISTRY
Volume 29, Issue 12, Pages 1508-1513Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b511049c
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The combination of the two positional isomers 1 and 2, porphyrin backbones bearing two pyridine N-oxide groups (PNO), with Zn(II) cations leads to 1-Zn and 2-Zn self-complementary tectons which generate in the crystalline phase analogous 1-D zigzag type coordination networks with different metrics. In both cases, only one PNO group bridges the consecutive tecton through coordination to the Zn atom which adopts the square based pyramidal geometry.
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