Journal
MOLECULES
Volume 10, Issue 1, Pages 195-200Publisher
MDPI
DOI: 10.3390/10010195
Keywords
radical; iodane; ether; vinyl sulfone; maleate
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Thermal decomposition of 1-tert-butylperoxy-1,2-benziodoxol-3(1H)-one in cyclic ethers and acetals at 50 degrees C generates alpha-oxy carbon-centered radicals, which undergo an addition reaction with vinyl sulfones and unsaturated esters.
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