Journal
JOURNAL OF WOOD SCIENCE
Volume 51, Issue 4, Pages 334-338Publisher
SPRINGER JAPAN KK
DOI: 10.1007/s10086-004-0667-6
Keywords
cellulose microfibril; matrix substance; wood cell wall; x-ray diffraction; water desorption
Categories
Ask authors/readers for more resources
We investigated mechanical interactions between the cellulose microfibril and the matrix substance in wood cell walls. X-ray diffraction measurements showed that the peak positions of (200) and (004) from cellulose crystals in wood cell walls tended to shift lower and higher toward 20, respectively, during water desorption in wood. From our simulations, it is shown that the peak shift of (200) during water desorption is not due to changes in the scattering pattern of the amorphous substance or to lateral expansion of the cellulose crystals due to the Poisson effect in the cellulose microfibril, which is compressed in the molecular chain direction as the amorphous substance shrinks. This suggests that the cellulose microfibril expands transversely during water desorption in the wood cell wall, and that there is a mechanical interaction between the cellulose microfibril and the matrix substance.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available