Journal
CARBON
Volume 141, Issue -, Pages 323-330Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2018.09.065
Keywords
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Funding
- bilateral Program Russian-German Laboratory at BESSY II in the part of XPS and NEXAFS measurements
- Federal Ministry of Education and Research [05K14OFA]
- Alexander von Humboldt Foundation from the Research Group Linkage Programme [3.4 -1007046 -RUS - IP]
- [0330-2016-0007]
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Hot pressing is one of the promising routes for graphitization of carbon materials. In the present work, high-pressure high-temperature behaviour of 13 C-enriched fine-grained graphitic material has been studied by using a set of experimental tools such as scanning electron microscopy, Raman scattering, Xray diffraction, X-ray photoelectron and near-edge X-ray absorption fine structure spectroscopies, and solid-state nuclear magnetic resonance (NMR) spectroscopy. The material has been annealed at a temperature of 1200 or 1500 degrees C using a stabilizing pressure of 5 GPa. It shown, that addition of small amount of water during the annealing at 1200 degrees C results in a better local atomic ordering of carbon material and increases the hydrocarbon fraction. Well-ordered graphite crystals enriched with C-13 isotope are formed on the surface of nickel ampule at 1500 degrees C. An increase in processing time from 2 to 15 h decreases the defect density and improves the graphitization level of the material. (C) 2018 Elsevier Ltd. All rights reserved.
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