Journal
CARBON
Volume 65, Issue -, Pages 156-164Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2013.08.009
Keywords
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Funding
- MICINN
- European Union [CSD2009-00050, MAT2010-16194]
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Graphene materials containing different functional groups were prepared from a natural graphite, by means of two different oxidation methods (Hummers and Brodie). It was observed that the differences in the structure of the resultant graphite oxides (GOs) greatly affect the structure of the graphenes resulting from their thermal exfoliation/reduction. Although the oxidation of the graphite was more effective with the modified Hummers method than with Brodie's method (C/O of 1.8 vs 2.9, as determined by XPS), the former generated a lower residual oxygen content after thermal exfoliation/reduction and a better reconstruction of the 2D graphene structure (with fewer defects). This is explained by the presence of conjugated epoxy and hydroxyl groups in the GO obtained by Brodie's method, which upon thermal treatment, lead to the incorporation of oxygen into the carbon lattice preventing its complete restoration. Additionally, graphene materials obtained with Brodie's method exhibit, in general, smaller sheet size and larger surface area. (C) 2013 Elsevier Ltd. All rights reserved.
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