Enhancement of CO2 adsorption on phenolic resin-based mesoporous carbons by KOH activation

Carbons with high surface area and large volume of ultramicropores were synthesized for CO2 adsorption. First, mesoporous carbons were produced by soft-templating method using triblock copolymer Pluronic F127 as a structure directing agent and formaldehyde and either phloroglucinol or resorcinol as carbon precursors. The resulting carbons were mainly mesoporous with well-developed surface area, large total pore volume, and only moderate CO2 uptake. To improve CO2 adsorption, these carbons were subjected to KOH activation to enhance their microporosity. Activated carbons showed 2-3-fold increase in the specific surface area, resulting from substantial development of microporosity (3-5-fold increase in the micropore volume). KOH activation resulted in enhanced CO2 adsorption at 760 mmHg pressure: 4.4 mrnol g(-1) at 25 degrees C, and 7 mmol g(-1) at 0 degrees C. This substantial increase in the CO2 uptake was achieved due to the development of ultramicroporosity, which was shown to be beneficial for CO2 physisorption at low pressures. The resulting materials were investigated using low-temperature nitrogen physisorption, CO2 sorption, and small-angle powder X-ray diffraction. High CO2 uptake and good cyclability (without noticeable loss in CO2 uptake after five runs) render ultramicroporous carbons as efficient CO2 adsorbents at ambient conditions. (C) 2013 Elsevier Ltd. All rights reserved.