4.8 Letter

The production of porosity in carbon nanofibers by the catalytic action of Ni nanoparticles in low temperature activation

Journal

CARBON
Volume 53, Issue -, Pages 409-413

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2012.11.017

Keywords

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Funding

  1. Korea Institute of Science and Technology Institutional program
  2. Fundamental R&D Program for Core Technology of Materials
  3. Ministry of Knowledge Economy, Republic of Korea

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Carbon nanofibers (CNFs) containing Ni nanoparticles were synthesized by carbonization of electrospun polyacrylonitrile nanofibers containing NiCl2 followed by low-temperature activation (similar to 325 degrees) in an oxygen atmosphere. The surface area of activated CNFs with 0.11 wt.% of the Ni oxide nanoparticles was 654 m(2)/g with increasing nanopores, which is significantly higher than the value for pure CNFs (30 m(2)/g). It was confirmed that the addition of trace amounts of Ni nanoparticles effectively produces a porous structure due to their catalytic role, which can increase the specific adsorption capacity of the activated CNFs without structural deformation.

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