Journal
SUPRAMOLECULAR CHEMISTRY
Volume 17, Issue 1-2, Pages 47-51Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/10610270412331328853
Keywords
target-oriented synthesis; supramolecular chemistry; linear template; solid-state reactions; cyclophane; ladderane
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We show that principles of supramolecular chemistry applied in the solid state provide a means to conduct target-oriented molecular syntheses. The syntheses are achieved using molecules that function as linear templates. The templates control molecular organization in the solid state by juxtaposing appropriately functionalized olefins for [2 + 2] photodimerization. We reveal that the linear templates can be used to construct a [2.2]cyclophane and [n]-ladderanes (where n = 3,5) as targets.
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