Journal
CARBON
Volume 50, Issue 2, Pages 518-525Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2011.09.007
Keywords
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Funding
- EU
- Spanish MCINN with FEDER [CSD2007-00010, CTQ-2008-06720, CTQ 2009-15896]
- Generalitat Valenciana
- Spanish ministry of Education
- Juan de la Cierva
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Mixing of aqueous suspensions of delaminated NiMn layered double hydroxide (LDH) and graphene oxide leads to the instantaneous precipitation of a hybrid material that after calcination under inert atmosphere at 450 degrees C leads to Ni6MnO8 nanoparticles deposited on larger reconstituted graphene sheets. This material exhibits electrical conductivity similar to graphite, superparamagnetism and can be used as an anode for Li-ion batteries. A maximum capacity value of 1030 mAh g(-1) was found during the first discharge, and capacity values higher than 400 mAh g(-1) were still achieved after 10 cycles. The methodology used here should allow the preparation of a large variety of hybrid graphene-metal oxide materials starting from other LDHs in which the properties derived from both constituents coexist. (C) 2011 Elsevier Ltd. All rights reserved.
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