Journal
CARBON
Volume 50, Issue 10, Pages 3957-3960Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2012.04.002
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A TiC-derived carbon (TiC-CDC) was prepared, and the adsorption of large hexacyanocobaltate and tetrabutylammonium ions of approximately same size was examined on this carbon. While selectively absorbing these large ions, it rejects smaller chloride and ammonium ions in mixed electrolyte solutions. The result demonstrates the important role of electrostatic repulsive forces, space-efficient charge packing and hydrophobic ion interactions with the pore walls of TiC-CDC, similar to what is known for a variety of biological membranes. (c) 2012 Elsevier Ltd. All rights reserved.
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