Journal
CARBON
Volume 49, Issue 15, Pages 5079-5089Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2011.07.027
Keywords
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Funding
- SCSR, Poland [N204 1115 35]
- NSF U.S. [DMR-0809129]
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1108636] Funding Source: National Science Foundation
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The room temperature oxidation of carbon nano-onions (CNOs) with ozone was investigated. The reaction was performed under mild conditions and oxidized products with high concentrations of oxygen-containing functional groups were obtained. The reaction products were characterized by Boehm titrations, additional oxidant/reductant treatments, and Raman and DRIFTS FT-IR spectroscopy. Electrochemical studies indicate changes in the surface chemistry of ozonized CNOs (oz-CNOs), exhibiting a larger total surface area and pore structure, which enables efficient accumulation of charge in the oz-CNOs film. (C) 2011 Elsevier Ltd. All rights reserved.
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