4.8 Article

Graphene oxide covalently functionalized with zinc phthalocyanine for broadband optical limiting

Journal

CARBON
Volume 49, Issue 6, Pages 1900-1905

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2011.01.014

Keywords

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Funding

  1. National Natural Science Foundation of China [20676034, 20876046]
  2. Ministry of Education of China [309013]
  3. Fundamental Research Funds for the Central Universities
  4. Shanghai Municipal Educational Commission [08GG10]
  5. Shanghai Eastern Scholarship
  6. SIOM, Chinese Academy of Sciences [1108221-JR0]

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A soluble graphene oxide (GO) covalently functionalized with zinc phthalocyanine (PcZn), GO-PcZn, was synthesized by an amidation reaction. The formation of an amido bond between PcZn and GO has been confirmed by X-ray photoelectron and Fourier transform infrared spectroscopy. At the same level of linear extinction coefficient, GO-PcZn exhibited much larger nonlinear optical extinction coefficients and broadband optical limiting performance than GO at both 532 and 1064 nm, indicating a remarkable accumulation effect as a result of the covalent link between GO and PcZn. (C) 2011 Elsevier Ltd. All rights reserved.

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