Journal
CARBON
Volume 49, Issue 2, Pages 693-700Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2010.10.022
Keywords
-
Funding
- Chinese Academy of Sciences
- Shangdong Province Funds for Distinguished Young Scientist
- National Natural Science Foundation of China [20901044, 20971077, 20902052]
Ask authors/readers for more resources
Graphene oxide nanoplatelets (GONPs) are presented as electrochemical active materials for VO2+/VO2+ and V2+/V3+ redox couples for a vanadium redox flow battery. The structures and electrochemical properties of GONPs treated at different temperatures were investigated by transmission electron microscopy, X-ray diffraction, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, Raman spectroscopy and cyclic voltammetry. The results indicate that GONPs treated at 50 degrees C (GONP-50) possess highly hydroxylated and carboxylated groups and exhibit an excellent electrocatalytic activity towards VO2+/VO2+ and V2+/V3+ redox couples, while the pristine graphite only shows a reversible electrocatalytic activity towards VO2+/VO2+, suggesting that the V2+/V3+ redox reaction more strongly depends on the oxygen-containing groups attached on graphite surface than does the VO2+/VO2+. With the increase of treatment temperature, the polarization is reduced significantly. GONPs treated at 120 degrees C (GNOP-120) exhibit a lower electrochemical polarization than that of GONP-50 because of relatively higher electrical conductivity despite moderate electrocatalytic activity. The diffusion of VO2+ is faster on the surface of GONP-50 than on the pristine graphite and GNOP-120. (C) 2010 Elsevier Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available