Journal
CARBON
Volume 46, Issue 2, Pages 229-235Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2007.11.007
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Sulfur coated mesoporous carbon (S-C) composites have been synthesized and physically characterized by scanning electron microscopy, transmission electron microscopy, Raman spectroscopy, and thermogravimetric analysis. Firstly, the electrochemical properties of the S-C composite cathode materials were tested in a conventional electrolyte consisting of 1 mol/L lithium bistrifluoromethanesulfonimidate in poly(ethylene glycol) dimethyl ether to compare them with pure sulfur electrode. The capacity and cyclic stability of the S-C composite were improved. Then the S-C composites were tested in a novel ionic liquid electrolyte consisting of 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide and lithium bistrifluoromethanesulfonimidate. The capacity and cyclic stability of the S-C composite using the ionic liquid electrolyte were much better than for the sample tested in a conventional organic solvent electrolyte. (c) 2007 Elsevier Ltd. All rights reserved..
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