Journal
CARBOHYDRATE RESEARCH
Volume 375, Issue -, Pages 68-72Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.carres.2013.04.003
Keywords
Sucrose; Scandium(III) chloride; 5-Hydroxymethylfurfual; Ionic liquids; Microwave irradiation
Funding
- National Natural Science Foundation of China [21203252]
- Special Fund for Basic Scientific Research of Central Colleges, South-Central University for Nationalities [CYZ2012005]
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In this study, synthesis of HMF from carbohydrates was carried out in ionic liquids 1-butyl-3-methylimidazolium chloride ([Bmim]Cl) catalyzed by ScCl3 under microwave irradiation. Under the optimal reaction conditions, HMF was obtained in a high yield of 73.4% in 2 mins with the microwave power at 400 W. Compared with the conventional oil-bath heating manner, the use of microwave irradiation not only reduced reaction times from hours to minutes, but also improved HMF yield. This catalytic system could be reused several times without losing its catalytic activity. This efficient catalytic system will generate a promising application strategy for biomass transformation. (C) 2013 Elsevier Ltd. All rights reserved.
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