4.5 Article

Straightforward glycosylation of alcohols and amino acids mediated by ionic liquid

Journal

CARBOHYDRATE RESEARCH
Volume 352, Issue -, Pages 202-205

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.carres.2012.03.004

Keywords

O-glycosylation; Glycosides; Glycopeptides; Amino acids; Ionic liquids; Green chemistry

Funding

  1. French Agence Nationale pour la Recherche [CP2D-GLYC-ENLI]

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Green glycosylation of functionalized alcohols and alpha-amino acids, using an ionic liquid as a recyclable solvent, was performed in one step directly from the unprotected monosaccharide under scandium triflate or ferric chloride catalysis. Pure alpha- and beta-glycosides could be obtained after specific enzymatic hydrolysis. (c) 2012 Elsevier Ltd. All rights reserved.

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