Journal
CARBOHYDRATE RESEARCH
Volume 356, Issue -, Pages 273-277Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.carres.2012.03.041
Keywords
Aldol reaction; Asymmetric synthesis; D-Glucosamine; Organocatalysis; L-Proline catalyst
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O-TBDPS D-glucosamine coupled with L-proline is reported to act as an efficient organocatalyst in the accomplishment of direct aldol reactions. Excellent results, in terms of chemical yields, as well as diastereomeric and enantiomeric ratios, are reported for the catalyzed additions of cyclohexanone and acetone to variously substituted benzaldehydes. (C) 2012 Elsevier Ltd. All rights reserved.
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