Journal
CARBOHYDRATE RESEARCH
Volume 346, Issue 16, Pages 2528-2532Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.carres.2011.08.023
Keywords
NaHSO4; Silica gel; Ferrier rearrangement; Glucal; Glycoside
Funding
- University of Johannesburg
- Research Center for Synthesis and Catalysis
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NaHSO4 supported on silica gel catalyses the Ferrier rearrangement reaction of 3,4,6-tri-O-acetyl-D-glucal with alcohols and thiols to give the corresponding 2,3-unsaturated glycosides in high anomeric selectivity and good to excellent yield in short reaction time. (C) 2011 Elsevier Ltd. All rights reserved.
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