Journal
CARBOHYDRATE RESEARCH
Volume 346, Issue 4, Pages 465-471Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.carres.2010.12.020
Keywords
Glycosyl amides; Glycosyl azides; Glycomimetics; Neoglycoconjugates; Staudinger ligation; Stereoselective synthesis
Funding
- Universita' degli Studi di Milano [PUR2008]
- Comune di Milano [Convenzione 55/2008]
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alpha- or beta-Galactofuranosyl (Gall) amides can be synthesized with high stereoselectivity by traceless Staudinger ligation starting from unprotected beta-galactofuranosyl azide or tetra-O-acetyl-beta-galactofuranosyl azide, respectively. The resulting Galf amides are hitherto unknown molecules, with interesting potential as inhibitors of mycobacterial growth. (C) 2011 Elsevier Ltd. All rights reserved.
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